Crystal structure and proton conductivity of a one-dimensional coordination polymer, {Mn(DHBQ)(H 2O) 2}

Shota Morikawa, Teppei Yamada, Hiroshi Kitagawa

研究成果: Contribution to journalArticle査読

55 被引用数 (Scopus)

抄録

{Mn(DHBQ)(H 2O) 2} (H 2DHBQ=2,5-dihydroxy-1, 4-benzoquinone) was investigated by X-ray diffraction, thermogravimetry, sorption isotherm of water, and proton conductivity measurements. It showed a one-dimensional coordination-polymer structure with axial coordination waters, which is the first report on the crystal structure of a one-dimensional coordination polymer with the DHBQ ligand. It also exhibited reversible structural change associated with desorption/sorption of the waters. The proton conductivities of the anhydride and dihydrate states were measured. The dihydrate showed a high proton conductivity of 4 × 10 -5 S cm -1, while the anhydride was below the lower limit of the measurable range (< 10 -13 S cm -1).

本文言語英語
ページ(範囲)654-655
ページ数2
ジャーナルChemistry Letters
38
7
DOI
出版ステータス出版済み - 7 20 2009

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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