The structure of the title complex has been determined. The crystal is orthorhombic, with the space group <I>Pnma</I>, <I>Z</I>=4, <I>a</I>=13.331 (2), <I>b</I>=16.130 (3), and <I>c</I>=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.
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