Crystal Structures of Azoarene-Capped Analogues of 1.10-Diaza-4,7,14,17-tetraoxa-and 1.10-Diaza-4,7,14,17-tetrathiacy clooc tadecane. Comparison of C-0 and C-S Bond Conformations in Capped Crown Analogues

Herman L. Ammon, Sovan K. Bhattacharjee, Seiji Shinkai, Yoshihiro Honda

研究成果: Contribution to journalArticle査読

17 被引用数 (Scopus)

抄録

Macropolycyclic polyethers contain intramolecular cavities lined with molecular segments capable of binding cations in three-dimensional cagelike structures. The Azoarene-capped O and S crown ethers (e.g., 1-3) undergo photoinduced reversible inter-Conversion between the trans and cis azo linkages, resulting in substantial changes in their cation binding properties.3 The X-ray structures of the azopyridine-capped analogue of l,10-diaza-18-crown-6 (1) and the azobenzene-capped sulfur analogue (3) have been determined as a step in understanding how ion selectivity and binding are controlled by the cavity structure. The conformations of the crown rings in 1 and 3 are substantially different from those of the “free” analogues, the latter containing the first example of the C-S anti conformation in a thiacrown macrocycle.

本文言語英語
ページ(範囲)262-263
ページ数2
ジャーナルJournal of the American Chemical Society
106
1
DOI
出版ステータス出版済み - 7 1984
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

フィンガープリント 「Crystal Structures of Azoarene-Capped Analogues of 1.10-Diaza-4,7,14,17-tetraoxa-and 1.10-Diaza-4,7,14,17-tetrathiacy clooc tadecane. Comparison of C-0 and C-S Bond Conformations in Capped Crown Analogues」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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