Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Benjamin Le Ouay; Haruka Yoshino; Kenta Sasaki; Yuta Ohtsubo; Ryo Ohtani; Masaaki Ohba

doi:10.1039/d1cc01185e

Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Benjamin Le Ouay, Haruka Yoshino, Kenta Sasaki, Yuta Ohtsubo, Ryo Ohtani, Masaaki Ohba

無機・分析化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

8 被引用数 (Scopus)

抄録

Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

本文言語	英語
ページ（範囲）	5187-5190
ページ数	4
ジャーナル	Chemical Communications
巻	57
号	42
DOI	https://doi.org/10.1039/d1cc01185e
出版ステータス	出版済み - 5月 25 2021

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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title = "Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates",

abstract = "Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.",

author = "{Le Ouay}, Benjamin and Haruka Yoshino and Kenta Sasaki and Yuta Ohtsubo and Ryo Ohtani and Masaaki Ohba",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry), JP18H01997, JP18K14245, JP19H04701 and JP20K22554. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = may,

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doi = "10.1039/d1cc01185e",

language = "English",

volume = "57",

pages = "5187--5190",

journal = "Chemical Communications",

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T1 - Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

AU - Le Ouay, Benjamin

AU - Yoshino, Haruka

AU - Sasaki, Kenta

AU - Ohtsubo, Yuta

AU - Ohtani, Ryo

AU - Ohba, Masaaki

N1 - Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry), JP18H01997, JP18K14245, JP19H04701 and JP20K22554. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/5/25

Y1 - 2021/5/25

N2 - Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

AB - Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

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AN - SCOPUS:85106561570

VL - 57

SP - 5187

EP - 5190

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 42

ER -

Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

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!!!All Science Journal Classification (ASJC) codes

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