Cyclo[m]pyridine[n]pyrroles: Hybrid macrocycles that display expanded π-conjugation upon protonation

Zhan Zhang; Jong Min Lim; Masatoshi Ishida; Vladimir V. Roznyatovskiy; Vincent M. Lynch; Han Yuan Gong; Xiaoping Yang; Dongho Kim; Jonathan L. Sessler

doi:10.1021/ja211985k

Cyclo[m]pyridine[n]pyrroles: Hybrid macrocycles that display expanded π-conjugation upon protonation

Zhan Zhang, Jong Min Lim, Masatoshi Ishida, Vladimir V. Roznyatovskiy, Vincent M. Lynch, Han Yuan Gong, Xiaoping Yang, Dongho Kim, Jonathan L. Sessler

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

62 被引用数 (Scopus)

抄録

Novel hybrid cyclo[m]pyridine[n]pyrroles have been synthesized using Suzuki coupling. Their NMR and optical spectroscopic features and solid state structural parameters provide support for the proposal that these species are best described as locally aromatic compounds devoid of long-range intersubunit conjugation. However, an extension of the π-conjugation in the macrocycles can be realized through protonation, as inferred from optical spectroscopic and X-ray diffraction-based structural studies.

本文言語	英語
ページ（範囲）	4076-4079
ページ数	4
ジャーナル	Journal of the American Chemical Society
巻	134
号	9
DOI	https://doi.org/10.1021/ja211985k
出版ステータス	出版済み - 3月 7 2012
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

文献へのアクセス

10.1021/ja211985k

他のファイルとリンク

引用スタイル

@article{e8f440af24e2483c87e647abdf601afe,

title = "Cyclo[m]pyridine[n]pyrroles: Hybrid macrocycles that display expanded π-conjugation upon protonation",

abstract = "Novel hybrid cyclo[m]pyridine[n]pyrroles have been synthesized using Suzuki coupling. Their NMR and optical spectroscopic features and solid state structural parameters provide support for the proposal that these species are best described as locally aromatic compounds devoid of long-range intersubunit conjugation. However, an extension of the π-conjugation in the macrocycles can be realized through protonation, as inferred from optical spectroscopic and X-ray diffraction-based structural studies.",

author = "Zhan Zhang and Lim, {Jong Min} and Masatoshi Ishida and Roznyatovskiy, {Vladimir V.} and Lynch, {Vincent M.} and Gong, {Han Yuan} and Xiaoping Yang and Dongho Kim and Sessler, {Jonathan L.}",

year = "2012",

month = mar,

day = "7",

doi = "10.1021/ja211985k",

language = "English",

volume = "134",

pages = "4076--4079",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Cyclo[m]pyridine[n]pyrroles

T2 - Hybrid macrocycles that display expanded π-conjugation upon protonation

AU - Zhang, Zhan

AU - Lim, Jong Min

AU - Ishida, Masatoshi

AU - Roznyatovskiy, Vladimir V.

AU - Lynch, Vincent M.

AU - Gong, Han Yuan

AU - Yang, Xiaoping

AU - Kim, Dongho

AU - Sessler, Jonathan L.

PY - 2012/3/7

Y1 - 2012/3/7

N2 - Novel hybrid cyclo[m]pyridine[n]pyrroles have been synthesized using Suzuki coupling. Their NMR and optical spectroscopic features and solid state structural parameters provide support for the proposal that these species are best described as locally aromatic compounds devoid of long-range intersubunit conjugation. However, an extension of the π-conjugation in the macrocycles can be realized through protonation, as inferred from optical spectroscopic and X-ray diffraction-based structural studies.

AB - Novel hybrid cyclo[m]pyridine[n]pyrroles have been synthesized using Suzuki coupling. Their NMR and optical spectroscopic features and solid state structural parameters provide support for the proposal that these species are best described as locally aromatic compounds devoid of long-range intersubunit conjugation. However, an extension of the π-conjugation in the macrocycles can be realized through protonation, as inferred from optical spectroscopic and X-ray diffraction-based structural studies.

UR - http://www.scopus.com/inward/record.url?scp=84863230536&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84863230536&partnerID=8YFLogxK

U2 - 10.1021/ja211985k

DO - 10.1021/ja211985k

M3 - Article

C2 - 22332703

AN - SCOPUS:84863230536

VL - 134

SP - 4076

EP - 4079

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 9

ER -

Cyclo[m]pyridine[n]pyrroles: Hybrid macrocycles that display expanded π-conjugation upon protonation

抄録

!!!All Science Journal Classification (ASJC) codes

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル