Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host

Naofumi Kobayashi, Hiroyuki Kuwae, Juro Oshima, Ryoichi Ishimatsu, Shuya Tashiro, Toshihiko Imato, Chihaya Adachi, Shuichi Shoji, Jun Mizuno

研究成果: Chapter in Book/Report/Conference proceedingConference contribution

抜粋

We developed a novel naphthalene-derivative to function as a wide-bandgap liquid organic semiconductor (LOS) host material for the limited range of liquid deep-blue light-emitting materials that have been developed to date. The naphthalene-derivative, 1-naphthaleneacetic acid 2-ethylhexyl ester (NLQ) was synthesized as a LOS, by introducing an ethylhexyl group into naphthalene. 9,10-Diphenyl anthracene (DPA) was doped into NLQ as a guest deep-blue dye. From the absorption spectrum, the bandgap energy of NLQ was estimated to be 4.13 eV, indicating that NLQ has the widest bandgap energy of any such host material so far as we know. Deep-blue electroluminescence (EL) emission in a liquid state was obtained by doping DPA into NLQ. Light emission could be achieved by a combination of Förster resonance energy transfer and direct recombination of trapped holes and electrons because the bandgap energy of DPA is straddle by that of the wide-bandgap NLQ. Thus, NLQ is shown to be a promising wide-bandgap LOS host material, which allows deep-blue light emission and may have applications in liquid organic light-emitting diodes.

元の言語英語
ホスト出版物のタイトルOrganic Photonic Materials and Devices XIX 2017
編集者Francois Kajzar, Toshikuni Kaino, Christopher E. Tabor, Yasuhiro Koike
出版者SPIE
ISBN(電子版)9781510606432
DOI
出版物ステータス出版済み - 1 1 2017
イベントOrganic Photonic Materials and Devices XIX 2017 - San Francisco, 米国
継続期間: 1 30 20172 1 2017

出版物シリーズ

名前Proceedings of SPIE - The International Society for Optical Engineering
10101
ISSN(印刷物)0277-786X
ISSN(電子版)1996-756X

その他

その他Organic Photonic Materials and Devices XIX 2017
米国
San Francisco
期間1/30/172/1/17

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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  • これを引用

    Kobayashi, N., Kuwae, H., Oshima, J., Ishimatsu, R., Tashiro, S., Imato, T., Adachi, C., Shoji, S., & Mizuno, J. (2017). Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. : F. Kajzar, T. Kaino, C. E. Tabor, & Y. Koike (版), Organic Photonic Materials and Devices XIX 2017 [101011B] (Proceedings of SPIE - The International Society for Optical Engineering; 巻数 10101). SPIE. https://doi.org/10.1117/12.2251640