Density measurements of the H2-CO2-CH4-CO-H2O System by the Isochoric Method at 722-930 K and 15.4-30.3 MPa

Siyuan Cheng, Fei Shang, Weigang Ma, Hui Jin, Naoya Sakoda, Xing Zhang, Liejin Guo

研究成果: ジャーナルへの寄稿記事

抄録

The density of the H2-CO2-CH4-CO-H2O system in the supercritical region of water is significant for analyzing the gasification process of organic substances in the supercritical water. We report density measurements of the quinary system by the isochoric method at 722-930 K and 15.4-30.3 MPa. The upper limit of the expanded uncertainty at 95% confidence for temperature is 0.2 K. The upper limits of the expanded relative uncertainties at 95% confidence for pressure and density are 0.0006 and 0.0125, respectively. The density data were compared with those predicted using the GERG-2008 equation of state. The absolute relative deviations between the calculated and experimental densities are not more than 1.79%. Furthermore, the excess volume of the quinary system decreases monotonically with the increase of temperature in the isochoric process at 722-930 K. The thermal expansion coefficients of the quinary system were also determined.

元の言語英語
ページ(範囲)4013-4023
ページ数11
ジャーナルJournal of Chemical and Engineering Data
64
発行部数9
DOI
出版物ステータス出版済み - 9 12 2019

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Carbon Monoxide
Water
Equations of state
Gasification
Thermal expansion
Temperature
Uncertainty

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

これを引用

Density measurements of the H2-CO2-CH4-CO-H2O System by the Isochoric Method at 722-930 K and 15.4-30.3 MPa. / Cheng, Siyuan; Shang, Fei; Ma, Weigang; Jin, Hui; Sakoda, Naoya; Zhang, Xing; Guo, Liejin.

:: Journal of Chemical and Engineering Data, 巻 64, 番号 9, 12.09.2019, p. 4013-4023.

研究成果: ジャーナルへの寄稿記事

Cheng, Siyuan ; Shang, Fei ; Ma, Weigang ; Jin, Hui ; Sakoda, Naoya ; Zhang, Xing ; Guo, Liejin. / Density measurements of the H2-CO2-CH4-CO-H2O System by the Isochoric Method at 722-930 K and 15.4-30.3 MPa. :: Journal of Chemical and Engineering Data. 2019 ; 巻 64, 番号 9. pp. 4013-4023.
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abstract = "The density of the H2-CO2-CH4-CO-H2O system in the supercritical region of water is significant for analyzing the gasification process of organic substances in the supercritical water. We report density measurements of the quinary system by the isochoric method at 722-930 K and 15.4-30.3 MPa. The upper limit of the expanded uncertainty at 95{\%} confidence for temperature is 0.2 K. The upper limits of the expanded relative uncertainties at 95{\%} confidence for pressure and density are 0.0006 and 0.0125, respectively. The density data were compared with those predicted using the GERG-2008 equation of state. The absolute relative deviations between the calculated and experimental densities are not more than 1.79{\%}. Furthermore, the excess volume of the quinary system decreases monotonically with the increase of temperature in the isochoric process at 722-930 K. The thermal expansion coefficients of the quinary system were also determined.",
author = "Siyuan Cheng and Fei Shang and Weigang Ma and Hui Jin and Naoya Sakoda and Xing Zhang and Liejin Guo",
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T1 - Density measurements of the H2-CO2-CH4-CO-H2O System by the Isochoric Method at 722-930 K and 15.4-30.3 MPa

AU - Cheng, Siyuan

AU - Shang, Fei

AU - Ma, Weigang

AU - Jin, Hui

AU - Sakoda, Naoya

AU - Zhang, Xing

AU - Guo, Liejin

PY - 2019/9/12

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N2 - The density of the H2-CO2-CH4-CO-H2O system in the supercritical region of water is significant for analyzing the gasification process of organic substances in the supercritical water. We report density measurements of the quinary system by the isochoric method at 722-930 K and 15.4-30.3 MPa. The upper limit of the expanded uncertainty at 95% confidence for temperature is 0.2 K. The upper limits of the expanded relative uncertainties at 95% confidence for pressure and density are 0.0006 and 0.0125, respectively. The density data were compared with those predicted using the GERG-2008 equation of state. The absolute relative deviations between the calculated and experimental densities are not more than 1.79%. Furthermore, the excess volume of the quinary system decreases monotonically with the increase of temperature in the isochoric process at 722-930 K. The thermal expansion coefficients of the quinary system were also determined.

AB - The density of the H2-CO2-CH4-CO-H2O system in the supercritical region of water is significant for analyzing the gasification process of organic substances in the supercritical water. We report density measurements of the quinary system by the isochoric method at 722-930 K and 15.4-30.3 MPa. The upper limit of the expanded uncertainty at 95% confidence for temperature is 0.2 K. The upper limits of the expanded relative uncertainties at 95% confidence for pressure and density are 0.0006 and 0.0125, respectively. The density data were compared with those predicted using the GERG-2008 equation of state. The absolute relative deviations between the calculated and experimental densities are not more than 1.79%. Furthermore, the excess volume of the quinary system decreases monotonically with the increase of temperature in the isochoric process at 722-930 K. The thermal expansion coefficients of the quinary system were also determined.

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