Deprotonation of organic compounds bearing acid protons promoted by metal amido complexes with chiral diamine ligands leading to new organometallic compounds

Kunihiko Murata, Hirokazu Konishi, Masato Ito, Takao Ikariya

研究成果: Contribution to journalArticle査読

63 被引用数 (Scopus)

抄録

Well-defined 16-electron metal amido complexes bearing chiral Ts-diamine ligands readily react with nitromethane, acetone, or phenylacetylene to give new organometallic compounds in almost quantitative yields. For example, an Ir amido complex, Cp*Ir[(R,R)Tscydn], reacts with nitromethane at room temperature to give quantitatively a nitromethyl Ir complex, Cp*Ir(CH2NO2)[(R,R)-Tscydn], as a single diastereomer. The isolable organometallic compounds with chiral amine ligands are relevant to active catalysts for asymmetric C-C bond formation.

本文言語英語
ページ(範囲)253-255
ページ数3
ジャーナルOrganometallics
21
2
DOI
出版ステータス出版済み - 2 4 2002
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

フィンガープリント

「Deprotonation of organic compounds bearing acid protons promoted by metal amido complexes with chiral diamine ligands leading to new organometallic compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル