Design and characterization of a polarized coordination polymer of a zinc(II) biphenyldicarboxylate bearing a sulfone group

Katsuhiko Kanaizuka; Shoji Iwakiri; Teppei Yamada; Hiroshi Kitagawa

doi:10.1246/cl.2010.28

Design and characterization of a polarized coordination polymer of a zinc(II) biphenyldicarboxylate bearing a sulfone group

Katsuhiko Kanaizuka, Shoji Iwakiri, Teppei Yamada, Hiroshi Kitagawa

応用化学

研究成果: Contribution to journal › Article › 査読

14 被引用数 (Scopus)

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A novel coordination polymer of zinc(II) biphenyldicarboxylate bearing a sulfone group, [Zn(sbdc)(H₂O)3]·(H2sbdc)· H ₂O (H₂sbdc: sulfone biphenyldicarboxylic acid), has been synthesized. It is composed of a one-dimensional chain structure of alternating Zn(II) cations and sbdc anions. This coordination polymer possesses noncoordinating uncharged acid H₂sbdc existing between the chains with hydrogen-bonding networks. The proton conductivity of [Zn(sbdc)(H ₂O)₃]· (H₂sbdc) · H₂O strongly depended on the relative humidity (RH), being 2.5 x 10^-7 S cm^-1 at 95% RH. The activation energy for proton conductivity was estimated to be 0.32 eV at 95% RH.

本文言語	英語
ページ（範囲）	28-29
ページ数	2
ジャーナル	Chemistry Letters
巻	39
号	1
DOI	https://doi.org/10.1246/cl.2010.28
出版ステータス	出版済み - 2010

All Science Journal Classification (ASJC) codes

化学 (全般)

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10.1246/cl.2010.28

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abstract = "A novel coordination polymer of zinc(II) biphenyldicarboxylate bearing a sulfone group, [Zn(sbdc)(H2O)3]·(H2sbdc)· H 2O (H2sbdc: sulfone biphenyldicarboxylic acid), has been synthesized. It is composed of a one-dimensional chain structure of alternating Zn(II) cations and sbdc anions. This coordination polymer possesses noncoordinating uncharged acid H2sbdc existing between the chains with hydrogen-bonding networks. The proton conductivity of [Zn(sbdc)(H 2O)3]· (H2sbdc) · H2O strongly depended on the relative humidity (RH), being 2.5 x 10-7 S cm-1 at 95% RH. The activation energy for proton conductivity was estimated to be 0.32 eV at 95% RH.",

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T1 - Design and characterization of a polarized coordination polymer of a zinc(II) biphenyldicarboxylate bearing a sulfone group

AU - Kanaizuka, Katsuhiko

AU - Iwakiri, Shoji

AU - Yamada, Teppei

AU - Kitagawa, Hiroshi

PY - 2010

Y1 - 2010

N2 - A novel coordination polymer of zinc(II) biphenyldicarboxylate bearing a sulfone group, [Zn(sbdc)(H2O)3]·(H2sbdc)· H 2O (H2sbdc: sulfone biphenyldicarboxylic acid), has been synthesized. It is composed of a one-dimensional chain structure of alternating Zn(II) cations and sbdc anions. This coordination polymer possesses noncoordinating uncharged acid H2sbdc existing between the chains with hydrogen-bonding networks. The proton conductivity of [Zn(sbdc)(H 2O)3]· (H2sbdc) · H2O strongly depended on the relative humidity (RH), being 2.5 x 10-7 S cm-1 at 95% RH. The activation energy for proton conductivity was estimated to be 0.32 eV at 95% RH.

AB - A novel coordination polymer of zinc(II) biphenyldicarboxylate bearing a sulfone group, [Zn(sbdc)(H2O)3]·(H2sbdc)· H 2O (H2sbdc: sulfone biphenyldicarboxylic acid), has been synthesized. It is composed of a one-dimensional chain structure of alternating Zn(II) cations and sbdc anions. This coordination polymer possesses noncoordinating uncharged acid H2sbdc existing between the chains with hydrogen-bonding networks. The proton conductivity of [Zn(sbdc)(H 2O)3]· (H2sbdc) · H2O strongly depended on the relative humidity (RH), being 2.5 x 10-7 S cm-1 at 95% RH. The activation energy for proton conductivity was estimated to be 0.32 eV at 95% RH.

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Design and characterization of a polarized coordination polymer of a zinc(II) biphenyldicarboxylate bearing a sulfone group

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