抄録
A novel coordination polymer of zinc(II) biphenyldicarboxylate bearing a sulfone group, [Zn(sbdc)(H2O)3]·(H2sbdc)· H 2O (H2sbdc: sulfone biphenyldicarboxylic acid), has been synthesized. It is composed of a one-dimensional chain structure of alternating Zn(II) cations and sbdc anions. This coordination polymer possesses noncoordinating uncharged acid H2sbdc existing between the chains with hydrogen-bonding networks. The proton conductivity of [Zn(sbdc)(H 2O)3]· (H2sbdc) · H2O strongly depended on the relative humidity (RH), being 2.5 x 10-7 S cm-1 at 95% RH. The activation energy for proton conductivity was estimated to be 0.32 eV at 95% RH.
本文言語 | 英語 |
---|---|
ページ(範囲) | 28-29 |
ページ数 | 2 |
ジャーナル | Chemistry Letters |
巻 | 39 |
号 | 1 |
DOI | |
出版ステータス | 出版済み - 2010 |
外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 化学 (全般)