Design and synthesis of optically active trans-chelating diphosphine ligands. Application for catalytic asymmetric synthesis

Yoshihiko Ito, Ryoichi Kuwano

研究成果: ジャーナルへの寄稿記事

11 引用 (Scopus)

抜粋

New chiral diphosphines 2,2"-bis[1-(disubstituted phosphino)ethyl]-1,1"-biferrocene, having both central and planar elements of chirality, was designed for a trans-chelating chiral diphosphine ligand (TRAP) for transition metals and synthesized form optically active N,N-dimethyl-1-ferrocenyl ethylamine. Some transition-metal complexes with the TRAP ligands were prepared and utilized as a chiral catalyst for asymmetric synthetic reactions.

元の言語英語
ページ(範囲)469-472
ページ数4
ジャーナルPhosphorus, Sulfur and Silicon and Related Elements
144-146
DOI
出版物ステータス出版済み - 1 1 1999
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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