Design of a dynamic polymer interface for chiral discrimination

Atsuomi Shundo, Koichiro Hori, Takuya Ikeda, Nobuo Kimizuka, Keiji Tanaka

    研究成果: ジャーナルへの寄稿学術誌査読

    45 被引用数 (Scopus)

    抄録

    Enantioselective wetting of a chiral polymer film was demonstrated. The contact angle of chiral liquids on the film was strongly dependent on their chirality although their physical properties including surface tension were identical. Such wetting behavior resulted from the enantioselective surface reorganization involving local conformational change of the polymer chains at the liquid interface. The concept of "dynamic interface for chiral discrimination" has possible potential for the development of materials capable of chiral sensing, optical resolution, and asymmetric synthesis.

    本文言語英語
    ページ(範囲)10282-10285
    ページ数4
    ジャーナルJournal of the American Chemical Society
    135
    28
    DOI
    出版ステータス出版済み - 7月 17 2013

    !!!All Science Journal Classification (ASJC) codes

    • 触媒
    • 化学 (全般)
    • 生化学
    • コロイド化学および表面化学

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