Design of an assembly of poly(benzimidazole), carbon nanotubes, and Pt nanoparticles for a fuel-cell electrocatalyst with an ideal interfacial nanostructure

Minoru Okamoto, Tsuyohiko Fujigaya, Naotoshi Nakashima

    研究成果: Contribution to journalArticle査読

    159 被引用数 (Scopus)

    抄録

    A newly designed and fabricated novel nanocomposite composed of multiwalled carbon nanotubes (MWNTs), poly(benzimidazole) (PBI), and Pt nanoparticles. This composite is fabricated by the preparation of PBI-wrapped MWNTs (MWNT/PBI), followed by Pt loading onto the MWNT/ PBI. As a result of the PBI wrapping, the loading efficiency of the Pt nanoparticles onto the MWNTs is dramatically improved up to 58.8% compared to that of the pristine MWNTs (41.0%). The process also allows homogeneous Pt immobilization onto the surface of MWNTs without any strong oxidation process for the MWNTs that is typically used for metal supporting on carbon nanotubes. Far-IR spectroscopy of the composite shows a peak from the Pt-N bonding, indicating that these improvements are derived from the coordination of the Pt ion with the PBI molecules. Cyclic voltammogram measurements reveal that the Pt nanoparticles deposited on the MWNT/PBI shows higher utilization efficiency (74%) for electrocatalysts compared to that on the pristine MWNT (39%).

    本文言語英語
    ページ(範囲)735-740
    ページ数6
    ジャーナルSmall
    5
    6
    DOI
    出版ステータス出版済み - 3 20 2009

    All Science Journal Classification (ASJC) codes

    • バイオテクノロジー
    • 生体材料
    • 化学 (全般)
    • 材料科学(全般)

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