Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety

Masakazu Higuchi, Kohei Nakamura, Satoshi Horike, Yuh Hijikata, Nobuhiro Yanai, Tomohiro Fukushima, Jungeun Kim, Kenichi Kato, Masaki Takata, Daisuke Watanabe, Shinji Oshima, Susumu Kitagawa

研究成果: ジャーナルへの寄稿記事

56 引用 (Scopus)

抄録

Charged up: A novel porous coordination polymer with a charged organic surface (COS) comprising a zwitterionic organic linker, viologen, has been synthesized. The COS shows strong Lewis acidity accompanied with flexibility, and the isosteric heat of H2 adsorption is 9.5 kJ mol-1, which is comparable to that of open metal sites (OMSs).

元の言語英語
ページ(範囲)8369-8372
ページ数4
ジャーナルAngewandte Chemie - International Edition
51
発行部数33
DOI
出版物ステータス出版済み - 8 13 2012

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Viologens
Polymers
Acidity
Metals
Adsorption

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety. / Higuchi, Masakazu; Nakamura, Kohei; Horike, Satoshi; Hijikata, Yuh; Yanai, Nobuhiro; Fukushima, Tomohiro; Kim, Jungeun; Kato, Kenichi; Takata, Masaki; Watanabe, Daisuke; Oshima, Shinji; Kitagawa, Susumu.

:: Angewandte Chemie - International Edition, 巻 51, 番号 33, 13.08.2012, p. 8369-8372.

研究成果: ジャーナルへの寄稿記事

Higuchi, M, Nakamura, K, Horike, S, Hijikata, Y, Yanai, N, Fukushima, T, Kim, J, Kato, K, Takata, M, Watanabe, D, Oshima, S & Kitagawa, S 2012, 'Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety', Angewandte Chemie - International Edition, 巻. 51, 番号 33, pp. 8369-8372. https://doi.org/10.1002/anie.201203834
Higuchi, Masakazu ; Nakamura, Kohei ; Horike, Satoshi ; Hijikata, Yuh ; Yanai, Nobuhiro ; Fukushima, Tomohiro ; Kim, Jungeun ; Kato, Kenichi ; Takata, Masaki ; Watanabe, Daisuke ; Oshima, Shinji ; Kitagawa, Susumu. / Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety. :: Angewandte Chemie - International Edition. 2012 ; 巻 51, 番号 33. pp. 8369-8372.
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AU - Yanai, Nobuhiro

AU - Fukushima, Tomohiro

AU - Kim, Jungeun

AU - Kato, Kenichi

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AU - Oshima, Shinji

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