抄録
High-density syndiotactic poly(methyl methacrylate) (st-PMMA) brushes form a helical structure and encapsulate fullerene molecules in their helical cavities, leading to a PMMA brush/fullerene inclusion complex. The brushes recognize the size of guest molecules and spontaneously adapt their helical diameter to the guest molecules. Both polymer brush/C60 and polymer brush/C70 inclusion complex on the flat substrate were characterized on the basis of grazing incidence wide-angle X-ray diffraction (GIWAXD) measurements, and it is revealed that the main chains oriented perpendicular to the substrate. Moreover, high-density st-PMMA brushes grafted onto nanoparticles efficiently separate C70 molecules from the mixture of C60 and C70 solution. Even after 5× repeating process, the selectivity for C70 molecules remains at 99%.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 148-152 |
| ページ数 | 5 |
| ジャーナル | ACS Macro Letters |
| 巻 | 7 |
| 発行部数 | 2 |
| DOI | |
| 出版物ステータス | 出版済み - 2 20 2018 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
これを引用
Design of High-Density Helical Polymer Brush on Silica Nanoparticles for the Size Recognition of Fullerene Molecules. / Sato, Masanao; Kato, Tomoki; Shimamoto, Hitoshi; Kamitani, Kazutaka; Ohta, Noboru; Hirai, Tomoyasu; Takahara, Atsushi.
：: ACS Macro Letters, 巻 7, 番号 2, 20.02.2018, p. 148-152.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - Design of High-Density Helical Polymer Brush on Silica Nanoparticles for the Size Recognition of Fullerene Molecules
AU - Sato, Masanao
AU - Kato, Tomoki
AU - Shimamoto, Hitoshi
AU - Kamitani, Kazutaka
AU - Ohta, Noboru
AU - Hirai, Tomoyasu
AU - Takahara, Atsushi
PY - 2018/2/20
Y1 - 2018/2/20
N2 - High-density syndiotactic poly(methyl methacrylate) (st-PMMA) brushes form a helical structure and encapsulate fullerene molecules in their helical cavities, leading to a PMMA brush/fullerene inclusion complex. The brushes recognize the size of guest molecules and spontaneously adapt their helical diameter to the guest molecules. Both polymer brush/C60 and polymer brush/C70 inclusion complex on the flat substrate were characterized on the basis of grazing incidence wide-angle X-ray diffraction (GIWAXD) measurements, and it is revealed that the main chains oriented perpendicular to the substrate. Moreover, high-density st-PMMA brushes grafted onto nanoparticles efficiently separate C70 molecules from the mixture of C60 and C70 solution. Even after 5× repeating process, the selectivity for C70 molecules remains at 99%.
AB - High-density syndiotactic poly(methyl methacrylate) (st-PMMA) brushes form a helical structure and encapsulate fullerene molecules in their helical cavities, leading to a PMMA brush/fullerene inclusion complex. The brushes recognize the size of guest molecules and spontaneously adapt their helical diameter to the guest molecules. Both polymer brush/C60 and polymer brush/C70 inclusion complex on the flat substrate were characterized on the basis of grazing incidence wide-angle X-ray diffraction (GIWAXD) measurements, and it is revealed that the main chains oriented perpendicular to the substrate. Moreover, high-density st-PMMA brushes grafted onto nanoparticles efficiently separate C70 molecules from the mixture of C60 and C70 solution. Even after 5× repeating process, the selectivity for C70 molecules remains at 99%.
UR - http://www.scopus.com/inward/record.url?scp=85042369980&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85042369980&partnerID=8YFLogxK
U2 - 10.1021/acsmacrolett.7b00906
DO - 10.1021/acsmacrolett.7b00906
M3 - Article
AN - SCOPUS:85042369980
VL - 7
SP - 148
EP - 152
JO - ACS Macro Letters
JF - ACS Macro Letters
SN - 2161-1653
IS - 2
ER -