Design of temperature-responsive polymers with enhanced hysteresis: α,α-disubstituted vinyl polymers

Takeshi Mori, Suguru Beppu, Mohamed R. Berber, Hironori Mori, Takumi Makimura, Ayako Tsukamoto, Keiji Minagawa, Tomohiro Hirano, Masami Tanaka, Takuro Niidome, Yoshiki Katayama, Tatsuya Hirano, Yasushi Maeda

    研究成果: Contribution to journalArticle査読

    18 被引用数 (Scopus)

    抄録

    Three temperature-responsive polymers which are R,R-disubstituted vinyl polymers having two amphiphilic groups (ethylamide or ethylester) per monomeric unit were designed. Two of these polymers showed unusually large hysteresis in their phase transition temperatures between a heating and a cooling process. This hysteresis resulted from the extremely slow kinetics of the dissolution process of the aggregated polymer chains in the cooling process due to intraand interchain interactions including hydrogen bonding and hydrophobic interaction. The high density of the amphiphilic substituents on the polymer chain due to the α,α-disubstituted structure enhanced these intra- and interchain interactions. The large hysteresis was also observed in the volume change of a corresponding hydrogel. These new classes of temperature-responsive polymers are interesting materials because their large hystereses can be regarded as erasable memory function.

    本文言語英語
    ページ(範囲)9224-9232
    ページ数9
    ジャーナルLangmuir
    26
    12
    DOI
    出版ステータス出版済み - 6 15 2010

    All Science Journal Classification (ASJC) codes

    • 材料科学(全般)
    • 凝縮系物理学
    • 表面および界面
    • 分光学
    • 電気化学

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