Determination of the vapor-liquid coexistence curve and the critical parameters for refrigerant 502

Y. Higashi, M. Uematsu, K. Watanabe

研究成果: Contribution to journalArticle査読

14 被引用数 (Scopus)

抄録

The vapor-liquid coexistence curve for refrigerant 502 (R 502) near the critical point has been determined by visual observation of the disappearance of the meniscus. Twenty-six saturated densities between 262 and 899 kg· m-3 have been obtained within an experimental error in temperature and density of ± 10 mK and ± 0.5%, respectively. Using these results along the vapor-liquid coexistence curve, the critical parameters, i.e., the critical temperature Tc=355.37 ±0.01 K and the critical density ρc=555±3kg · m-3, have been determined based on the disappearance of the meniscus level as well as on the intensity of the critical opalescence. A critical pressure Pc=4.070±0.002 MPa has been calculated from the existing vapor-pressure correlation using the present Tcvalue. In addition, the critical exponent β along the coexistence curve and the law of rectilinear diameter near the critical point are discussed.

本文言語英語
ページ(範囲)117-129
ページ数13
ジャーナルInternational Journal of Thermophysics
5
2
DOI
出版ステータス出版済み - 6 1 1984
外部発表はい

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

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