Detrimental Effect of Unreacted PbI2 on the Long-Term Stability of Perovskite Solar Cells

Ganbaatar Tumen-Ulzii, Chuanjiang Qin, Dino Klotz, Matthew R. Leyden, Pangpang Wang, Morgan Auffray, Takashi Fujihara, Toshinori Matsushima, Jin Wook Lee, Sung Joon Lee, Yang Yang, Chihaya Adachi

研究成果: Contribution to journalArticle査読

48 被引用数 (Scopus)

抄録

Excess/unreacted lead iodide (PbI2) has been commonly used in perovskite films for the state-of-the-art solar cell applications. However, an understanding of intrinsic degradation mechanisms of perovskite solar cells (PSCs) containing unreacted PbI2 has been still insufficient and, therefore, needs to be clarified for better operational durability. Here, it is shown that degradation of PSCs is hastened by unreacted PbI2 crystals under continuous light illumination. Unreacted PbI2 undergoes photodecomposition under illumination, resulting in the formation of lead and iodine in films. Thus, this photodecomposition of PbI2 is one of the main reasons for accelerated device degradation. Therefore, this work reveals that carefully controlling the formation of unreacted PbI2 crystals in perovskite films is very important to improve device operational stability for diverse opto-electronic applications in the future.

本文言語英語
論文番号1905035
ジャーナルAdvanced Materials
32
16
DOI
出版ステータス出版済み - 4 1 2020

All Science Journal Classification (ASJC) codes

  • 材料科学(全般)
  • 材料力学
  • 機械工学

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