DFT study for selective adsorption of 1,3-dimethyltrisulfane responsible for aged odor in Japanese sake using supported gold nanoparticles

Ayaka Sonoura, Akihide Hayashi, Yoshinori Ato, Hiroaki Koga, Haruno Murayama, Makoto Tokunaga, Mitsutaka Okumura

研究成果: ジャーナルへの寄稿学術誌査読

抄録

Au nanoclusters (Au NCs) supported on SiO2 effectively adsorbed 1, 3-dimethyltrisulfane (DMTS), which is responsible for the aged odor of Japanese sake. Smaller-size Au NCs exhibited higher adsorption amount of DMTS than those of larger Au NCs. In order to investigate theoretically the selective adsorption of DMTS, density functional theory calculations were carried out for different sizes of Au NCs. These calculations showed that Au NCs decompose and adsorb DMTS selectively on the Au NC surface.

本文言語英語
ページ(範囲)218-221
ページ数4
ジャーナルChemistry Letters
49
3
DOI
出版ステータス出版済み - 2020

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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