Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Yoshimitsu Tachi, Kazuki Aita, Shinichi Teramae, Fumito Tani, Yoshinori Naruta, Shunichi Fukuzumi, Shinobu Itoh

研究成果: Contribution to journalArticle査読

30 被引用数 (Scopus)

抄録

A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η12 binding mode, the spectroscopic features and the reactivity of which have been explored in detail.

本文言語英語
ページ(範囲)4558-4560
ページ数3
ジャーナルInorganic Chemistry
43
15
DOI
出版ステータス出版済み - 7 26 2004

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 無機化学

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