Diffusion of technetium in compacted bentonites in the reducing condition with corrosion products of iron

Yuji Kuroda, K. Idemitsu, H. Furuya, Y. Inagaki, T. Arima

研究成果: ジャーナルへの寄稿Conference article

19 引用 (Scopus)

抄録

In the vicinity of a high-level waste repository, corrosion of carbon steel overpacks will create a reducing environment. Reducing conditions are expected to retard the migration of redox-sensitive radionuclides such as technetium. The apparent diffusion coefficients of technetium were measured in compacted bentonites (Kunigel V1 and Kunipia F, JAPAN) in contact with carbon steel and its corrosion products under reducing conditions or without carbon steel under oxidizing conditions for comparison. The apparent diffusion coefficients measured were 10-10 to 10-11 m2/s under oxidizing conditions and 10-12 to 10-13 m2/s under reducing conditions. There were significant effects of redox condition, dry density (0.2 to 2.3 g/cm3) and montmorillonite content (50% for Kunigel V1 or 100% for Kunipia F) on the apparent diffusion coefficients. Montmorillonite density could be a good index to explain density dependence of the diffusion coefficients under both reducing and oxidizing conditions.

元の言語英語
ページ(範囲)[d]909-916
ジャーナルMaterials Research Society Symposium - Proceedings
465
出版物ステータス出版済み - 1 1 1997
イベントProceedings of the 1996 MRS Fall Meeting - Boston, MA, USA
継続期間: 12 2 199612 6 1996

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technetium
Technetium
corrosion
Iron
Corrosion
Carbon steel
Bentonite
iron
steel
Clay minerals
montmorillonite
carbon
dry density
density dependence
redox conditions
Radioisotopes
repository
radionuclide
product
Oxidation-Reduction

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

これを引用

Diffusion of technetium in compacted bentonites in the reducing condition with corrosion products of iron. / Kuroda, Yuji; Idemitsu, K.; Furuya, H.; Inagaki, Y.; Arima, T.

:: Materials Research Society Symposium - Proceedings, 巻 465, 01.01.1997, p. [d]909-916.

研究成果: ジャーナルへの寄稿Conference article

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abstract = "In the vicinity of a high-level waste repository, corrosion of carbon steel overpacks will create a reducing environment. Reducing conditions are expected to retard the migration of redox-sensitive radionuclides such as technetium. The apparent diffusion coefficients of technetium were measured in compacted bentonites (Kunigel V1 and Kunipia F, JAPAN) in contact with carbon steel and its corrosion products under reducing conditions or without carbon steel under oxidizing conditions for comparison. The apparent diffusion coefficients measured were 10-10 to 10-11 m2/s under oxidizing conditions and 10-12 to 10-13 m2/s under reducing conditions. There were significant effects of redox condition, dry density (0.2 to 2.3 g/cm3) and montmorillonite content (50{\%} for Kunigel V1 or 100{\%} for Kunipia F) on the apparent diffusion coefficients. Montmorillonite density could be a good index to explain density dependence of the diffusion coefficients under both reducing and oxidizing conditions.",
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T1 - Diffusion of technetium in compacted bentonites in the reducing condition with corrosion products of iron

AU - Kuroda, Yuji

AU - Idemitsu, K.

AU - Furuya, H.

AU - Inagaki, Y.

AU - Arima, T.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - In the vicinity of a high-level waste repository, corrosion of carbon steel overpacks will create a reducing environment. Reducing conditions are expected to retard the migration of redox-sensitive radionuclides such as technetium. The apparent diffusion coefficients of technetium were measured in compacted bentonites (Kunigel V1 and Kunipia F, JAPAN) in contact with carbon steel and its corrosion products under reducing conditions or without carbon steel under oxidizing conditions for comparison. The apparent diffusion coefficients measured were 10-10 to 10-11 m2/s under oxidizing conditions and 10-12 to 10-13 m2/s under reducing conditions. There were significant effects of redox condition, dry density (0.2 to 2.3 g/cm3) and montmorillonite content (50% for Kunigel V1 or 100% for Kunipia F) on the apparent diffusion coefficients. Montmorillonite density could be a good index to explain density dependence of the diffusion coefficients under both reducing and oxidizing conditions.

AB - In the vicinity of a high-level waste repository, corrosion of carbon steel overpacks will create a reducing environment. Reducing conditions are expected to retard the migration of redox-sensitive radionuclides such as technetium. The apparent diffusion coefficients of technetium were measured in compacted bentonites (Kunigel V1 and Kunipia F, JAPAN) in contact with carbon steel and its corrosion products under reducing conditions or without carbon steel under oxidizing conditions for comparison. The apparent diffusion coefficients measured were 10-10 to 10-11 m2/s under oxidizing conditions and 10-12 to 10-13 m2/s under reducing conditions. There were significant effects of redox condition, dry density (0.2 to 2.3 g/cm3) and montmorillonite content (50% for Kunigel V1 or 100% for Kunipia F) on the apparent diffusion coefficients. Montmorillonite density could be a good index to explain density dependence of the diffusion coefficients under both reducing and oxidizing conditions.

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