Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

Shogo Kuriyama, Kazuya Arashiba, Hiromasa Tanaka, Yuki Matsuo, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

研究成果: Contribution to journalArticle査読

127 被引用数 (Scopus)

抄録

The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP-type pincer ligand. Up to 15.9 equivalents of ammonia were produced based on the amount of catalyst together with 1.0 equivalent of hydrazine (17.9 equiv of fixed nitrogen atoms).

本文言語英語
ページ(範囲)14291-14295
ページ数5
ジャーナルAngewandte Chemie - International Edition
55
46
DOI
出版ステータス出版済み - 11 7 2016

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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