Diversity in the reactions of unsymmetric dinucleating Schiff base ligands with Cu11 and Ni11

Harry Adams, David E. Fenton, Shabana R. Haque, Sarah L. Heath, Masaaki Ohba, Hisashi Okawa, Sharon E. Spey

研究成果: ジャーナルへの寄稿記事

79 引用 (Scopus)

抜粋

A diversity of reaction products have been found in the reactions of two related unsymmetrical Schiffbase dinucleating ligands, HL1 and HL2, derived from 3-chIoromethyl-5-methylsalicylaldehyde 1, with copper(n) and nickel(n) salts. The ligands remain intact in the copper(n) complexes to give the homodinuclear complexes [Cu2L'Br3] 2 and [Cu2L2(OH)(C1O4)]C1O4 3, the crystal structures of which have been solved. The reactions of HL1 and HL2 with nickel perchlorate led to hydrolysis of the imine bond. With HL1 the homodinuclear complex [NiLA(OH2)]2[ClO4]2'4H2O was formed and with HL2 hydrolysis was followed by elimination of C2H4 from the terminal NEt2 of the iminic side arm to leave an NHEt group and the dinuclear complex [NiLc(OH2)]2[ClO4]2-3CH3OH. The crystal structures of the two nickel complexes are also reported.

元の言語英語
ページ(範囲)1849-1856
ページ数8
ジャーナルJournal of the Chemical Society, Dalton Transactions
発行部数12
DOI
出版物ステータス出版済み - 1 1 2000

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント Diversity in the reactions of unsymmetric dinucleating Schiff base ligands with Cu<sup>11</sup> and Ni<sup>11</sup>' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用