Does Cob(II)alamin act as a conductor in coenzyme B12 dependent mutases?

Pawel M. Kozlowski, Takashi Kamachi, Tetsuo Toraya, Kazunari Yoshizawa

研究成果: ジャーナルへの寄稿学術誌査読

57 被引用数 (Scopus)

抄録

To conduct a concert of Co-C bond cleavage and subsequent H-atom abstraction may be the role of cob(II)alamin in coenzyme B12 dependent mutases (see picture, Ado = adenosyl). Evidence is presented on the basis of DFT analysis that these reactions are concerted and that the radicals generated during the catalytic process are stabilized by the presence of corrin. (Chemical Equation Presented).

本文言語英語
ページ(範囲)980-983
ページ数4
ジャーナルAngewandte Chemie - International Edition
46
6
DOI
出版ステータス出版済み - 2月 7 2007

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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