Doped CeO2-LaFeO3 composite oxide as an active anode for direct hydrocarbon-type solid oxide fuel cells

Tae Ho Shin, Shintaro Ida, Tatsumi Ishihara

    研究成果: Contribution to journalArticle査読

    130 被引用数 (Scopus)

    抄録

    Direct utilization of hydrocarbon and other renewable fuels is one of the most important issues concerning solid oxide fuel cells (SOFCs). Mixed ionic and electronic conductors (MIECs) have been explored as anode materials for direct hydrocarbon-type SOFCs. However, electrical conductivity of the most often reported MIEC oxide electrodes is still not satisfactory. As a result, mixed-conducting oxides with high electrical conductivity and catalytic activity are attracting considerable interest as an alternative anode material for noncoke depositing anodes. In this study, we examine the oxide composite Ce(Mn,Fe)O2-La(Sr)Fe(Mn)O3 for use as an oxide anode in direct hydrocarbon-type SOFCs. High performance was demonstrated for this composite oxide anode in direct hydrocarbon-type SOFCs, showing high maximum power density of approximately 1 W cm-2 at 1073 K when propane and butane were used as fuel. The high power density of the cell results from the high electrical conductivity of the composite oxide in hydrocarbon and the high surface activity in relation to direct hydrocarbon oxidation.

    本文言語英語
    ページ(範囲)19399-19407
    ページ数9
    ジャーナルJournal of the American Chemical Society
    133
    48
    DOI
    出版ステータス出版済み - 12 7 2011

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

    フィンガープリント 「Doped CeO<sub>2</sub>-LaFeO<sub>3</sub> composite oxide as an active anode for direct hydrocarbon-type solid oxide fuel cells」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル