抄録
(Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.
本文言語 | 英語 |
---|---|
ページ(範囲) | 8913-8916 |
ページ数 | 4 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 47 |
号 | 46 |
DOI | |
出版ステータス | 出版済み - 11月 3 2008 |
!!!All Science Journal Classification (ASJC) codes
- 触媒
- 化学 (全般)