Droplet nucleation on a well-defined hydrophilic-hydrophobic surface of 10 nm order resolution

Yutaka Yamada, Tatsuya Ikuta, Takashi Nishiyama, Koji Takahashi, Yasuyuki Takata

研究成果: Contribution to journalArticle査読

40 被引用数 (Scopus)

抄録

Water condensation on a hybrid hydrophilic-hydrophobic surface was investigated to reveal nucleation mechanisms at the microscale. Focused ion beam (FIB) irradiation was used to change the wettability of the hydrophobic surface with 10 nm order spatial resolution. Condensation experiments were conducted using environmental scanning electron microscopy; droplets, with a minimum diameter of 800 nm, lined up on the FIB-irradiated hydrophilic lines. The heterogeneous nucleation theory was extended to consider the water molecules attracted to the hydrophilic area, thereby enabling explanation of the nucleation mechanism under unsaturated conditions. Our results showed that the effective surface coverage of the water molecules on the hydrophilic region was 0.1-1.1 at 0.0 °C and 560 Pa and was dependent on the width of the FIB-irradiated hydrophilic lines and hydrophobic area. The droplet nucleation mechanism unveiled in this work would enable the design of new surfaces with enhanced dropwise condensation heat transfer. (Figure Presented).

本文言語英語
ページ(範囲)14532-14537
ページ数6
ジャーナルLangmuir
30
48
DOI
出版ステータス出版済み - 12 9 2014

All Science Journal Classification (ASJC) codes

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

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