Dual-component cholesterol-based gelators bearing complementary hydrogen-bonding sites

Sang Won Jeong, Kazutaka Murata, Seiji Shinkai

研究成果: ジャーナルへの寄稿記事

82 引用 (Scopus)

抄録

Cholesterol derivatives with an isocyanuric acid moiety 1 or a triaminopyrimidine moiety 2 were synthesized expecting a co-operative action between the hydrogen-bonding interaction and the cholesterol-cholesterol interaction to provide the reinforced aggregation property. Although 1 could gelatinize several organic solvents by itself, 2 always resulted in precipitates from these solvents. In contrast, a 1:1 1+2 mixture gave reinforced organic gels because of the action of their complementary hydrogen-bonding sites. IR spectroscopic studies showed, however, that the 1+2 gel does not employ a neat tape structure but a partially disordered, kinetically stable structure.

元の言語英語
ページ(範囲)83-86
ページ数4
ジャーナルSupramolecular Science
3
発行部数1-3
DOI
出版物ステータス出版済み - 1 1 1996
外部発表Yes

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Bearings (structural)
Cholesterol
Hydrogen bonds
Gels
Organic solvents
Tapes
Precipitates
Agglomeration
Derivatives
Acids

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Dual-component cholesterol-based gelators bearing complementary hydrogen-bonding sites. / Jeong, Sang Won; Murata, Kazutaka; Shinkai, Seiji.

:: Supramolecular Science, 巻 3, 番号 1-3, 01.01.1996, p. 83-86.

研究成果: ジャーナルへの寄稿記事

Jeong, Sang Won ; Murata, Kazutaka ; Shinkai, Seiji. / Dual-component cholesterol-based gelators bearing complementary hydrogen-bonding sites. :: Supramolecular Science. 1996 ; 巻 3, 番号 1-3. pp. 83-86.
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