Effect of conformational changes and differences of proteins on frictional properties of poly(vinyl alcohol) hydrogel

Kazuhiro Nakashima, Yoshinori Sawae, Teruo Murakami

研究成果: ジャーナルへの寄稿記事

14 引用 (Scopus)

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In this study, albumin or γ-globulin, both of which are included in natural synovial fluid, was used as an additive into lubricants to investigate the ability to reduce the friction for poly(vinyl alcohol) hydrogel in mixed lubrication. It was found from a measurement in circular dichroism that albumin contains a large amount of α-helix structure and γ-globulin contains a large amount of β-sheet structure. The lubricant containing only albumin showed low friction compared to the lubricant containing only γ-globulin. The effect of protein boundary film was clarified by changing lubricant. Albumin kept the friction low after changing from γ-globulin used at initial rubbing, but γ-globulin increased the friction after changing from albumin at initial rubbing. From a sliding distance of 600 m, albumin showed lower friction but γ-globulin showed higher friction. Therefore, in the case of friction decreasing, γ-globulin forms a tight adsorbed layer and subsequently albumin forms a layer with low shearing strength. Hence, it is important to apply the adsorption layer of γ-globulin at the bottom and make a layered structure composed of albumin and γ-globulin to reduce both friction and wear.

元の言語英語
ページ(範囲)1423-1427
ページ数5
ジャーナルTribology International
40
発行部数10-12 SPEC. ISS.
DOI
出版物ステータス出版済み - 10 1 2007

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All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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