TY - CONF
T1 - Effect of hydrogen peroxide on separation of chalcopyrite and molybdenite using flotation
AU - Wisnu Suyantara, Gde Pandhe
AU - Hirajima, Tsuyoshi
AU - Miki, Hajime
AU - Sasaki, Keiko
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Science Research (JSPS KAKENHI) from the Japan Society for the Promotion of Science (JSPS) – Japan [Grant numbers JP15H02333 and JP26∙04378)]; The Sumitomo Metal Mining Co., Ltd.; and the Ministry of Education, Culture, Sports, Science and Technology Japan (MEXT).
Publisher Copyright:
©The Mining and Materials Processing Institute of Japan
PY - 2017
Y1 - 2017
N2 - Various oxidation treatments (i.e., plasma, and ozone) have been applied to separate molybdenite from other sulfide metals. However, plasma and ozone treatments exhibit stronger oxidation on chalcopyrite and molybdenite, reducing the separation selectivity of both minerals in flotation tests. On the other hand, hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in wastewater treatment. It has also been reported to reduce the recovery of sulfide minerals. Therefore, the effect of H2O2 on separation of chalcopyrite and molybdenite was investigated in this study. Contact angle readings and surface images using atomic force microscopy (AFM) showed that chalcopyrite surface was more sensitive to surface oxidation compared to that of molybdenite in H2O2 aqueous solution. The floatability test of single mineral confirmed the contact angle results and AFM images, indicating a possibility for selective separation of chalcopyrite and molybdenite using a H2O2 aqueous solution. In addition, iron was used to improve the oxidation performance of H2O2 and its effect on the selective flotation of chalcopyrite and molybdenite is intensively studied in this work.
AB - Various oxidation treatments (i.e., plasma, and ozone) have been applied to separate molybdenite from other sulfide metals. However, plasma and ozone treatments exhibit stronger oxidation on chalcopyrite and molybdenite, reducing the separation selectivity of both minerals in flotation tests. On the other hand, hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in wastewater treatment. It has also been reported to reduce the recovery of sulfide minerals. Therefore, the effect of H2O2 on separation of chalcopyrite and molybdenite was investigated in this study. Contact angle readings and surface images using atomic force microscopy (AFM) showed that chalcopyrite surface was more sensitive to surface oxidation compared to that of molybdenite in H2O2 aqueous solution. The floatability test of single mineral confirmed the contact angle results and AFM images, indicating a possibility for selective separation of chalcopyrite and molybdenite using a H2O2 aqueous solution. In addition, iron was used to improve the oxidation performance of H2O2 and its effect on the selective flotation of chalcopyrite and molybdenite is intensively studied in this work.
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M3 - Paper
AN - SCOPUS:85065991228
T2 - 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017
Y2 - 26 September 2017 through 29 September 2017
ER -