Effect of interfacial interaction on mechanical properties of (polyurethane/organo-clay) composites

Miguru Motokucho, Ken Ichi Isumura, Ken Kojio, Mutsuhisa Furukawa

研究成果: Contribution to conferencePaper

抄録

(Polyurethane/organo-clay) composites (PUCs) were synthesized from 4, 4′ -diphenyl methanediisocyanate (MDI), 1,4-butanediol (BD), poly(oxytetramethylene) glycol (PTMG, Mn=1979) and organo-clay. The organo-clays (DTAB-clay and NC12OH-clay) were prepared from dodecyltrimethylammonium bromide (DTAB) and hydroxyldodecyltrimethylammonium bromide (NC12OH) with natural-clay, respectively. And co-intercalated organo-clay (DTAB-NC12OH-clay) was prepared from DTAB, NC12OH and natural-clay. The expansion of distance between layer of organo-clays and mechanical properties of PUCs were investigated by wide angle X-ray diffraction (WAXD) and tensile testing, respectively. And the DTAB-NC12OH-PUC and DTAB-PUC show peak at the lower angle than organo-clay in the WAXD profile. However, NC12OH-PUC showed no new peak in the WAXD profile. The DTAB-PUC and NC12OH-PUC showed decreasing tensile strength and strain at break. The DTAB-NC12OH-PUC showed good mechanical property compared with other PUC. These results suggested that the interfacial interaction affected to mechanical property of PUC.

本文言語英語
ページ3387-3388
ページ数2
出版ステータス出版済み - 12 1 2006
外部発表はい
イベント55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, 日本
継続期間: 9 20 20069 22 2006

その他

その他55th Society of Polymer Science Japan Symposium on Macromolecules
Country日本
CityToyama
Period9/20/069/22/06

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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