Effect of low surface energy chain ends on the glass transition temperature of polymer thin films

Fengchao Xie, Tianbai He, H. F. Zhang, Fuk Kay Lee, Binyang Du, Ophelia K.C. Tsui, Y. Yokoe, Keiji Tanaka, Atsushi Takahara, T. Kajiyama

研究成果: ジャーナルへの寄稿記事

64 引用 (Scopus)

抄録

The Tg of thin films of PS with sec-butyl-initiated proton terminations and those with the lower energy fluoroalkylsilyl termination was measured. In comparison, the latter exhibit a drastically higher reduction in the Tg with decreasing film thickness. The result evidences the first time that a surface layer sufficiently plasticized by segregated chain ends may have a global effect on the Tg of a polymer film.

元の言語英語
ページ(範囲)1491-1492
ページ数2
ジャーナルMacromolecules
35
発行部数5
DOI
出版物ステータス出版済み - 2 26 2002

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Interfacial energy
Polymer films
Film thickness
Protons
Thin films
Glass transition temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

これを引用

Xie, F., He, T., Zhang, H. F., Lee, F. K., Du, B., Tsui, O. K. C., ... Kajiyama, T. (2002). Effect of low surface energy chain ends on the glass transition temperature of polymer thin films. Macromolecules, 35(5), 1491-1492. https://doi.org/10.1021/ma011689a

Effect of low surface energy chain ends on the glass transition temperature of polymer thin films. / Xie, Fengchao; He, Tianbai; Zhang, H. F.; Lee, Fuk Kay; Du, Binyang; Tsui, Ophelia K.C.; Yokoe, Y.; Tanaka, Keiji; Takahara, Atsushi; Kajiyama, T.

:: Macromolecules, 巻 35, 番号 5, 26.02.2002, p. 1491-1492.

研究成果: ジャーナルへの寄稿記事

Xie, F, He, T, Zhang, HF, Lee, FK, Du, B, Tsui, OKC, Yokoe, Y, Tanaka, K, Takahara, A & Kajiyama, T 2002, 'Effect of low surface energy chain ends on the glass transition temperature of polymer thin films', Macromolecules, 巻. 35, 番号 5, pp. 1491-1492. https://doi.org/10.1021/ma011689a
Xie, Fengchao ; He, Tianbai ; Zhang, H. F. ; Lee, Fuk Kay ; Du, Binyang ; Tsui, Ophelia K.C. ; Yokoe, Y. ; Tanaka, Keiji ; Takahara, Atsushi ; Kajiyama, T. / Effect of low surface energy chain ends on the glass transition temperature of polymer thin films. :: Macromolecules. 2002 ; 巻 35, 番号 5. pp. 1491-1492.
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AU - Tsui, Ophelia K.C.

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AU - Takahara, Atsushi

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