Effect of microstructure of polyisoprene on miscibility of poly(4-trimethylsilylstyrene)/polyisoprene blend

Kana Takei; Daisuke Kawaguchi; Atsushi Takano; Yushu Matsushtta

Effect of microstructure of polyisoprene on miscibility of poly(4-trimethylsilylstyrene)/polyisoprene blend

Kana Takei, Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushtta

研究成果: 会議への寄与タイプ › 学会誌 › 査読

抄録

Miscibility of poly(4-trimethylsilylstyrene)(PTMSS) / l,4-polyisoprene(l,4- PI) blend was studied by differential scanning calorimetry (DSC) in conjunction with optical microscopy, and the result was compared with that for PTMSS/1,2- and 3,4-polyisoprene (vinyl-PI). PTMSS / 1,4-PI blend was miscible at room temperature and its phase diagram exhibited a lower critical solution temperature (LCST). At the same molecular weight, the LCST of PTMSS / vinyl-PI blend was at least higher than 473 K but that of PTMSS / 1,4-PI blend was 368 K. This means that the miscibility of 1,4-PI with PTMSS is much lower than that of vinyl-PI.

本文言語	英語
ページ数	1
出版ステータス	出版済み - 12月 1 2005
外部発表	はい
イベント	54th SPSJ Annual Meeting 2005 - Yokohama, 日本継続期間: 5月 25 2005 → 5月 27 2005

その他

その他	54th SPSJ Annual Meeting 2005
国/地域	日本
City	Yokohama
Period	5/25/05 → 5/27/05

!!!All Science Journal Classification (ASJC) codes

工学（全般）

他のファイルとリンク

引用スタイル

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title = "Effect of microstructure of polyisoprene on miscibility of poly(4-trimethylsilylstyrene)/polyisoprene blend",

abstract = "Miscibility of poly(4-trimethylsilylstyrene)(PTMSS) / l,4-polyisoprene(l,4- PI) blend was studied by differential scanning calorimetry (DSC) in conjunction with optical microscopy, and the result was compared with that for PTMSS/1,2- and 3,4-polyisoprene (vinyl-PI). PTMSS / 1,4-PI blend was miscible at room temperature and its phase diagram exhibited a lower critical solution temperature (LCST). At the same molecular weight, the LCST of PTMSS / vinyl-PI blend was at least higher than 473 K but that of PTMSS / 1,4-PI blend was 368 K. This means that the miscibility of 1,4-PI with PTMSS is much lower than that of vinyl-PI.",

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T1 - Effect of microstructure of polyisoprene on miscibility of poly(4-trimethylsilylstyrene)/polyisoprene blend

AU - Takei, Kana

AU - Kawaguchi, Daisuke

AU - Takano, Atsushi

AU - Matsushtta, Yushu

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Miscibility of poly(4-trimethylsilylstyrene)(PTMSS) / l,4-polyisoprene(l,4- PI) blend was studied by differential scanning calorimetry (DSC) in conjunction with optical microscopy, and the result was compared with that for PTMSS/1,2- and 3,4-polyisoprene (vinyl-PI). PTMSS / 1,4-PI blend was miscible at room temperature and its phase diagram exhibited a lower critical solution temperature (LCST). At the same molecular weight, the LCST of PTMSS / vinyl-PI blend was at least higher than 473 K but that of PTMSS / 1,4-PI blend was 368 K. This means that the miscibility of 1,4-PI with PTMSS is much lower than that of vinyl-PI.

AB - Miscibility of poly(4-trimethylsilylstyrene)(PTMSS) / l,4-polyisoprene(l,4- PI) blend was studied by differential scanning calorimetry (DSC) in conjunction with optical microscopy, and the result was compared with that for PTMSS/1,2- and 3,4-polyisoprene (vinyl-PI). PTMSS / 1,4-PI blend was miscible at room temperature and its phase diagram exhibited a lower critical solution temperature (LCST). At the same molecular weight, the LCST of PTMSS / vinyl-PI blend was at least higher than 473 K but that of PTMSS / 1,4-PI blend was 368 K. This means that the miscibility of 1,4-PI with PTMSS is much lower than that of vinyl-PI.

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T2 - 54th SPSJ Annual Meeting 2005

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Effect of microstructure of polyisoprene on miscibility of poly(4-trimethylsilylstyrene)/polyisoprene blend

抄録

その他

!!!All Science Journal Classification (ASJC) codes

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