Effect of oxidation state of iron ions on the viscosity of alkali silicate melts

Takeshi Osugi, Sohei Sukenaga, Yosuke Inatomi, Yoshiaki Gonda, Noritaka Saito, Kunihiko Nakashima

    研究成果: ジャーナルへの寄稿学術誌査読

    18 被引用数 (Scopus)

    抄録

    Understanding the changes in viscosity due to the different oxidation states of iron ions is important for simulating phenomena related to molten slags and also for understanding the structure of iron-oxidecontaining silicate melts. However, these viscosity changes are not well understood. Here, we show the viscosity changes of R2O-SiO2-FexO (R = Li, Na, or K melts due to changes in the oxidation states of the iron ions by systematically varying the oxygen partial pressure using several Ar-based gases at 1 773 K. The initial compositions of the samples were 30R2O-60SiO 2-10Fe2O3 (mol%), and the ratio of Fe 3+ to Fe2+ in the R2O-SiO2-FexO melts increased with increasing oxygen partial pressure in all samples. Meanwhile, the viscosity of all the R2O-SiO2-FexO melts decreased with increasing Fe2+ to total-Fe ratio. The data indicate that the increase in the amount of Fe2+ ions, which behave as network modifiers, would result in depolymerization of the silicate melts. It should also be noted that the viscosity of the melts increased in the order of alkali cationic radius (K > Na > Li when the ratios of Fe2+ to Fe 3+ in the melts were comparable. This was due to the change in the coordination structure of Fe3+ in the melts. Not only the oxidation state of the iron ions but also the coordination structure of Fe3+ may be important for understanding the viscosity.

    本文言語英語
    ページ(範囲)185-190
    ページ数6
    ジャーナルisij international
    53
    2
    DOI
    出版ステータス出版済み - 2013

    !!!All Science Journal Classification (ASJC) codes

    • 材料力学
    • 機械工学
    • 金属および合金
    • 材料化学

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