Effect of preparation methods on NOx removal ability by sorption in Pt-ZrO2-Al2O3

Suzue Kikuyama, Izumi Matsukuma, Ryuji Kikuchi, Kazunari Sasaki, Koichi Eguchi

研究成果: Contribution to journalArticle査読

10 被引用数 (Scopus)


Heterogeneous porous materials of Pt-ZrO2-Al2O3 are prepared via three different procedures based on impregnation and/or ammonia precipitation to examine their ability for NOx removal by sorption. In case a sample was prepared via ammonia precipitation, the sample exhibited both a larger BET surface area and a higher NO removal ability than a sample prepared only via impregnation. The experimental results indicate that a high-temperature calcination is essential to remove residual Cl from Pt-ZrO2-Al2O3 prepared from H2PtCl6 in order to provide more active NOx sorption sites. This suggestion was supported by the experimental results: (1) the sample prepared using H2PtCl6 as a Pt source should be calcined at a higher temperature after the Pt source was added in order to exhibit a higher sorption ability, and (2) the use of Cl-free Pt sources enhanced the NOx sorptio n capacity even after calcination at a lower temperature.

ジャーナルApplied Catalysis A: General
出版ステータス出版済み - 10 5 2001

All Science Journal Classification (ASJC) codes

  • 触媒
  • プロセス化学およびプロセス工学


「Effect of preparation methods on NO<sub>x</sub> removal ability by sorption in Pt-ZrO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。