Effects of additives on RuO2(10 wt%)/La0.6Sr0.4CoO3 anode for increasing sensitivity of solid oxide amperometric CO Sensor

Tatsumi Ishihara, Jun Iwata

    研究成果: Contribution to journalArticle査読

    2 被引用数 (Scopus)

    抄録

    An amperometric CO sensor using a solid oxide electrolyte was studied and it was found that the oxygen pumping current increased with increasing CO concentration when Au(10 wt%)/In1.9Sn0.1O3 and RuO2(10 wt%)/La0.6Sr0.4CoO3(LSC) were used for cathode and anode, respectively and La0.9Sr0.1Ga0.8Mg0.2O3 as the electrolyte. Changes in oxygen pumping current was caused by difference in electrode activity to CO oxidation upon exposure to CO and so sensitivity is strongly dependent on difference in electrode activity. Effects of additives to RuO2/LSC electrode on CO sensitivity were studied and it was found that addition of Pt is highly effective for increasing CO sensitivity. This could be explained by increased oxidation activity to CO. Further addition of Pd as the second additive to Pt-RuO2/LSC was effective for achieving high sensitivity and the highest CO sensitivity in our previous study was achieved on this type sensor. Amperometric sensor using RuO2-PtPd/LSC and Au/ITO anode and cathode, respectively, shows the high sensitivity to CO and so this sensor is promising as a CO sensor directly inserted into exhaust gas.

    本文言語英語
    ページ(範囲)535-539
    ページ数5
    ジャーナルSensors and Actuators, B: Chemical
    223
    DOI
    出版ステータス出版済み - 2 1 2016

    All Science Journal Classification (ASJC) codes

    • 電子材料、光学材料、および磁性材料
    • 器械工学
    • 凝縮系物理学
    • 表面、皮膜および薄膜
    • 金属および合金
    • 電子工学および電気工学
    • 材料化学

    フィンガープリント

    「Effects of additives on RuO<sub>2</sub>(10 wt%)/La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3</sub> anode for increasing sensitivity of solid oxide amperometric CO Sensor」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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