Effects of Ce0.6Mn0.3Fe0.1O2-δ interlayer on electrochemical properties of microtubular SOFC using doped LaGaO3 electrolyte

Kohei Hosoi, Takaaki Sakai, Shintaro Ida, Tatsumi Ishihara

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

Effects of Ce0.6Mn0.3Fe0.1O2-δ (CMF) anodic interlayer on power generation properties of microtubular SOFC using doped La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) electrolyte were investigated. Two types of microtubular cells, which were used NiOCe0.8Gd0.2O2-δ (GDC) cerment for anode porous substrate, were prepared with (A-cell) or without (B-cell) CMF interlayer by dip-coating method. The power generation properties of A- and B-cell sintered at 1623 K were measured. It was revealed that A-cell showed about 40% higher power density (1 W/cm2 at 973 K) than that of B-cell at temperature from 873 to 973 K because of the decreased electrode polarization by introducing CMF anodic interlayer. It was found that the diffusion of Ni into LSGM/Ti-LDC (Ce0.6La0.4O2-δ added with 0.5 wt% TiO2) interlayer was much suppressed by CMF interlayer (A-cell). This is because Ni was trapped in the CMF interlayer and formed Ni-CMF composite layer. Decrease in the polarization resistance might be assigned to the formation of Ni-CMF composite layer. Thus, CMF is promising for increasing the power generation property of microtubular SOFC using LSGM electrolyte prepared by dip coating method.

本文言語英語
ページ(範囲)F1379-F1383
ジャーナルJournal of the Electrochemical Society
162
12
DOI
出版ステータス出版済み - 1 1 2015

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

フィンガープリント

「Effects of Ce<sub>0.6</sub>Mn<sub>0.3</sub>Fe<sub>0.1</sub>O<sub>2-δ</sub> interlayer on electrochemical properties of microtubular SOFC using doped LaGaO<sub>3</sub> electrolyte」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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