Effects of nanofiller surface structure on the properties of polymer hybrid thin films

Nao Hosaka, Hideyuki Otsuka, Naoya Torikai, Osami Sakata, Atsushi Takahara

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

Polymer thin films are thermally not stable, and will easily dewet from the substrate. In this study, the strategy to suppress the dewetting of polystyrene (PS) thin films by the addition of polyhedral oligomeric silsesquioxanes (POSS) as a nanofiller was proposed. The addition of cyclopentyl-substituted POSS (cPOSS) to the PS thin films led to a great inhibition of dewetting. Structural analyses revealed that cPOSS segregated on the film surface and crystallized. Neutron reflectivity measurement showed that the interfacial structure was also roughened by the addition of cPOSS. On the other hand, isobutyl-substituted POSS did not form such interface enrichment layers. This difference of the dispersion state influenced the dewetting properties of the films. The inhibition of dewettng can be attributed to the modification of surface and interface by the segregation of cPOSS.

元の言語英語
ホスト出版物のタイトル54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan
ページ892
ページ数1
54
エディション1
出版物ステータス出版済み - 2005
イベント54th SPSJ Annual Meeting 2005 - Yokohama, 日本
継続期間: 5 25 20055 27 2005

その他

その他54th SPSJ Annual Meeting 2005
日本
Yokohama
期間5/25/055/27/05

Fingerprint

Surface structure
Thin films
Polystyrenes
Polymers
Polymer films
Neutrons
Substrates

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Hosaka, N., Otsuka, H., Torikai, N., Sakata, O., & Takahara, A. (2005). Effects of nanofiller surface structure on the properties of polymer hybrid thin films. : 54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan (1 版, 巻 54, pp. 892)

Effects of nanofiller surface structure on the properties of polymer hybrid thin films. / Hosaka, Nao; Otsuka, Hideyuki; Torikai, Naoya; Sakata, Osami; Takahara, Atsushi.

54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan. 巻 54 1. 編 2005. p. 892.

研究成果: 著書/レポートタイプへの貢献会議での発言

Hosaka, N, Otsuka, H, Torikai, N, Sakata, O & Takahara, A 2005, Effects of nanofiller surface structure on the properties of polymer hybrid thin films. : 54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan. 1 Edn, 巻. 54, pp. 892, 54th SPSJ Annual Meeting 2005, Yokohama, 日本, 5/25/05.
Hosaka N, Otsuka H, Torikai N, Sakata O, Takahara A. Effects of nanofiller surface structure on the properties of polymer hybrid thin films. : 54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan. 1 版 巻 54. 2005. p. 892
Hosaka, Nao ; Otsuka, Hideyuki ; Torikai, Naoya ; Sakata, Osami ; Takahara, Atsushi. / Effects of nanofiller surface structure on the properties of polymer hybrid thin films. 54th SPSJ Annual Meeting 2005 - Polymer Preprints, Japan. 巻 54 1. 版 2005. pp. 892
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