Effects of the structure of the Rh3+modifier on photocatalytic performances of an Rh3+/TiO2photocatalyst under irradiation of visible light

Sho Kitano, Masaaki Sadakiyo, Kenichi Kato, Miho Yamauchi, Hiroyuki Asakura, Tsunehiro Tanaka, Keiji Hashimoto, Hiroshi Kominami

    研究成果: Contribution to journalArticle査読

    4 被引用数 (Scopus)

    抄録

    For a rhodium ion-modified TiO2(Rh3+/TiO2) photocatalyst responding to visible light, control of the structure of the Rh3+modifier and effects of the structures of the Rh3+modifier on photocatalytic activities were examined. A TiO2support was pre-calcined to maintain crystallinity and specific surface area during post-calcination, and the structure of the Rh3+modifier for Rh3+/TiO2was changed by post-calcination without causing changes in the crystallinity and specific surface area of the TiO2support. In mineralization of acetone under irradiation of visible light, the photocatalytic activities of the post-calcined Rh3+/TiO2showed a volcano-like tendency as a function of post-calcination temperature. The results of this study showed that an atomically isolated structure of the Rh3+modifier was preferable for high activities and that aggregation of the Rh species led to a decrease in the activities.

    本文言語英語
    ページ(範囲)340-346
    ページ数7
    ジャーナルApplied Catalysis B: Environmental
    205
    DOI
    出版ステータス出版済み - 2017

    All Science Journal Classification (ASJC) codes

    • 触媒
    • 環境科学(全般)
    • プロセス化学およびプロセス工学

    フィンガープリント

    「Effects of the structure of the Rh<sup>3+</sup>modifier on photocatalytic performances of an Rh<sup>3+</sup>/TiO<sub>2</sub>photocatalyst under irradiation of visible light」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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