Effects of the structure of the Rh3+modifier on photocatalytic performances of an Rh3+/TiO2photocatalyst under irradiation of visible light

Sho Kitano, Masaaki Sadakiyo, Kenichi Kato, Miho Yamauchi, Hiroyuki Asakura, Tsunehiro Tanaka, Keiji Hashimoto, Hiroshi Kominami

研究成果: ジャーナルへの寄稿記事

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For a rhodium ion-modified TiO2(Rh3+/TiO2) photocatalyst responding to visible light, control of the structure of the Rh3+modifier and effects of the structures of the Rh3+modifier on photocatalytic activities were examined. A TiO2support was pre-calcined to maintain crystallinity and specific surface area during post-calcination, and the structure of the Rh3+modifier for Rh3+/TiO2was changed by post-calcination without causing changes in the crystallinity and specific surface area of the TiO2support. In mineralization of acetone under irradiation of visible light, the photocatalytic activities of the post-calcined Rh3+/TiO2showed a volcano-like tendency as a function of post-calcination temperature. The results of this study showed that an atomically isolated structure of the Rh3+modifier was preferable for high activities and that aggregation of the Rh species led to a decrease in the activities.

元の言語英語
ページ(範囲)340-346
ページ数7
ジャーナルApplied Catalysis B: Environmental
205
DOI
出版物ステータス出版済み - 1 1 2017

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

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