Electrochemical and photochemical cyclization and cycloreversion of diarylethenes and diarylethene-capped sexithiophene wires

Aleksandar Staykov, Jetsuda Areephong, Wesley R. Browne, Ben L. Feringa, Kazunari Yoshizawa

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A combined theoretical and experimental study was performed on diarylethenes and diarylethene-capped sexithiophenes aiming at an improved understanding of the electrochemical and photochemical ring-opening and ring-closing mechanisms. Theoretical calculations, based on DFT and TDDFT, suggested that the spatial distribution and the occupancy of the frontier orbitals determine and control the diarylethenes' ring-opening and ring-closing upon photoirradiation and electrochemical oxidation. Optimized geometries, potential energy surfaces, and activation energies between the open-ring and closed-ring forms were calculated for diarylethenes in the neutral ground state, excited states, and mono- and dicationic states. Analysis of the frontier orbitals was employed to understand the cyclization and cycloreversion of diarylethenes and to predict and explain the switching properties of diarylethene-capped sexithiophene molecular wires. The TDDFT data were verified with experimentally measured UV/vis spectra. The DFT calculations estimated open-shell ground states of diarylethene-capped sexithiophene dications, which were verified with EPR spectroscopy, and the broadening of the peaks in the EPR spectra were explained with the calculated singlet-triplet splitting. The good agreement of experiment and theory allows for the understanding of switching behavior of diarylethenes in solutions, in metal break junctions, in monolayers on metal surfaces, and as a part of complex organic molecular wires.

元の言語英語
ページ(範囲)1165-1178
ページ数14
ジャーナルACS nano
5
発行部数2
DOI
出版物ステータス出版済み - 2 22 2011

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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