Electrochemical catalytic carbon-skeleton rearrangement mediated by imine/oxime-type B12 model complex

Keishiro Tahara, Yi Chen, Ling Pan, Takahiro Masuko, Hisashi Shimakoshi, Yoshio Hisaeda

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

An electrochemical carbon-skeleton rearrangement of methylmalonate skeleton to succinate was successfully mediated by an imine/oxime-type cobalt complex using diethyl 2-bromomethyl-2- phenylmalonate as a model substrate of a coenzyme B12-dependent enzymatic reaction. Cyclic voltammetric and mass spectrometric studies revealed that this electrocatalysis of the alkyl bromide with 1,2-migration of a carboxylic ester group was achieved by the duet redox process between the reduction of the monoalkylated complex and the oxidation of the dialkylated complex.

本文言語英語
ページ(範囲)177-179
ページ数3
ジャーナルChemistry Letters
40
2
DOI
出版ステータス出版済み - 2011

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント 「Electrochemical catalytic carbon-skeleton rearrangement mediated by imine/oxime-type B<sub>12</sub> model complex」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル