Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12

Yoshio Hisaeda, Hisashi Shimakoshi, Mami Tokunaga, Tatsushi Baba

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

The controlled-potential electrolysis of 1,1-bis(4-chlorophenyl)-2,2,2- trichloroethane (DDT) was carried out in the presence of a hydrophobic vitamin B12, heptamethyl cobyrinate perchlorate. DDT was dechlorinated to form 1,1-bis(4-chlorophenyl)-2,2-dichloroethane (DDD), 1,1-bis(4-chlorophenyl)- 2,2-dichloroethylene (DDE), 1-chloro-2,2-bis(4-chlorophenyl)ethylene (DDMU) and 1,1,4,4-tetrakis(4-chlorophenyl)-2,3-dichloro-2-butene (TTDB) (E/Z), and quantitative recovery of the catalyst after the electrolysis was confirmed by the electronic spectroscopy. A photo-sensitive intermediate having a cobalt-carbon bond formed during the electrolysis was characterized by the electronic spectroscopy. The mechanism for the formation of various dehalogenated products was investigated by various spectroscopic methods.

元の言語英語
ホスト出版物のタイトルAnalytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda
編集者J. Lessard, P. Hapiot, I. Taniguchi
ページ13-16
ページ数4
10
出版物ステータス出版済み - 2004
イベントAnalytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda - San Antonio, TX, 米国
継続期間: 5 9 20045 14 2004

その他

その他Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda
米国
San Antonio, TX
期間5/9/045/14/04

Fingerprint

Dehalogenation
Vitamins
Electrolysis
Spectroscopy
Butenes
Cobalt
Ethylene
Recovery
Catalysts
Carbon

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Hisaeda, Y., Shimakoshi, H., Tokunaga, M., & Baba, T. (2004). Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12 : J. Lessard, P. Hapiot, & I. Taniguchi (版), Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda (巻 10, pp. 13-16)

Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12 . / Hisaeda, Yoshio; Shimakoshi, Hisashi; Tokunaga, Mami; Baba, Tatsushi.

Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda. 版 / J. Lessard; P. Hapiot; I. Taniguchi. 巻 10 2004. p. 13-16.

研究成果: 著書/レポートタイプへの貢献会議での発言

Hisaeda, Y, Shimakoshi, H, Tokunaga, M & Baba, T 2004, Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12 : J Lessard, P Hapiot & I Taniguchi (版), Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda. 巻. 10, pp. 13-16, Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda, San Antonio, TX, 米国, 5/9/04.
Hisaeda Y, Shimakoshi H, Tokunaga M, Baba T. Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12 : Lessard J, Hapiot P, Taniguchi I, 編集者, Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda. 巻 10. 2004. p. 13-16
Hisaeda, Yoshio ; Shimakoshi, Hisashi ; Tokunaga, Mami ; Baba, Tatsushi. / Electrochemical dehalogenation reaction of DDT mediated by hydrophobic vitamin B12 Analytical, Mechanistic, and Synthetic Organic Electrochemistry - The Sixth International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda. 編集者 / J. Lessard ; P. Hapiot ; I. Taniguchi. 巻 10 2004. pp. 13-16
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