Electrochemical fixation of CO2 to organohalides in room-temperature ionic liquids under supercritical CO2

Hiroyuki Tateno, Koji Nakabayashi, Tsuneo Kashiwagi, Hisanori Senboku, Mahito Atobe

研究成果: ジャーナルへの寄稿学術誌査読

25 被引用数 (Scopus)

抄録

The electrochemical properties of novel reaction media, ionic liquid (IL)/supercritical CO2 (scCO2) systems, were evaluated and the electrochemical carboxylation of various organohalides in these systems was demonstrated. Voltammetric studies revealed that the CO2 solubility in an IL such as N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]) increased in the presence of scCO2. The IL/scCO2 systems were found to be effective for the electrochemical carboxylation of various organohalides.

本文言語英語
ページ(範囲)212-218
ページ数7
ジャーナルElectrochimica Acta
161
DOI
出版ステータス出版済み - 4月 10 2015
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学工学(全般)
  • 電気化学

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