Electrochemical oxidation of 1,3,5-tris(diphenylamino)benzene (TDAB) for polyradical material

Kazunari Yoshizawa, Akihiro Ito, Kazuyoshi Tanaka, Tokio Yamabe

研究成果: Contribution to journalArticle

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Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 1019 g-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation.

元の言語英語
ページ(範囲)81-83
ページ数3
ジャーナルSynthetic Metals
66
発行部数1
DOI
出版物ステータス出版済み - 9 15 1994
外部発表Yes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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