Electrochemically driven, cobalt-carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF2)4X

Luxia Cui, Toshikazu Ono, Md Jakir Hossain, Yoshio Hisaeda

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

A proof-of-concept for the one-step, synthetically challenging cyclic and acyclic perfluoroalkylation of (hetero)arenes driven by the valence change of a vitamin B12 derivative as a cobalt catalyst in the presence of fluoroalkylating reagents (X(CF2)4X) is presented. The consecutive formation of cobalt-carbon bonds and generation of fluoroalkyl radicals by homolysis are the key steps for the reaction to proceed.

本文言語英語
ページ(範囲)24862-24866
ページ数5
ジャーナルRSC Advances
10
42
DOI
出版ステータス出版済み - 6 30 2020

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)

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