2,2'-ビス[2,2-ジアリールエテニル]ビフェニル型電子供与体のエレクトロキロオプティカル応答

博紀 樋口; 英輔 太田; 英敏 河合; 孝紀 鈴木; 孝 辻

doi:10.11494/kisoyuki.16.0.1021.0

2,2'-ビス[2,2-ジアリールエテニル]ビフェニル型電子供与体のエレクトロキロオプティカル応答

樋口博紀, 太田英輔, 河合英敏, 鈴木孝紀, 辻孝

融合材料部門

研究成果: Contribution to journal › Article

抄録

A biphenyl-type electron donor 1a with two diarylmethylene chromophores was prepared, which gave a dihydrophenanthrene-type dication 2a2+ upon oxidation. It is shown that the redox pair of 1a and 2a2+ exhibits electrochromism accompanied by reversible C-C bond making/breaking. On the other hand, the binaphthyl derivative of 1a is chiral due to the axial chirality, thus realizing a chiroptical response by electron transfer. The title compounds were shown to be a useful skeleton to obtain the multi-output response system based on chiral redox systems, for which only a limited numbers of successful examples were reported.

寄稿の翻訳タイトル	Electrochiroptical Response of a 2,2'-Bis[2,2-diarylethenyl]biphenyl-type Electron Donor
本文言語	未定義
ページ（範囲）	1021-1021
ページ数	1
ジャーナル	基礎有機化学討論会要旨集（基礎有機化学連合討論会予稿集）
巻	16
号	0
DOI	https://doi.org/10.11494/kisoyuki.16.0.1021.0
出版ステータス	出版済み - 2002

文献へのアクセス

10.11494/kisoyuki.16.0.1021.0

フィンガープリント「2,2'-ビス[2,2-ジアリールエテニル]ビフェニル型電子供与体のエレクトロキロオプティカル応答」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "A biphenyl-type electron donor 1a with two diarylmethylene chromophores was prepared, which gave a dihydrophenanthrene-type dication 2a2+ upon oxidation. It is shown that the redox pair of 1a and 2a2+ exhibits electrochromism accompanied by reversible C-C bond making/breaking. On the other hand, the binaphthyl derivative of 1a is chiral due to the axial chirality, thus realizing a chiroptical response by electron transfer. The title compounds were shown to be a useful skeleton to obtain the multi-output response system based on chiral redox systems, for which only a limited numbers of successful examples were reported.",

author = "博紀樋口 and 英輔太田 and 英敏河合 and 孝紀鈴木 and 孝辻",

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T1 - 2,2'-ビス[2,2-ジアリールエテニル]ビフェニル型電子供与体のエレクトロキロオプティカル応答

AU - 樋口, 博紀

AU - 太田, 英輔

AU - 河合, 英敏

AU - 鈴木, 孝紀

AU - 辻, 孝

PY - 2002

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N2 - A biphenyl-type electron donor 1a with two diarylmethylene chromophores was prepared, which gave a dihydrophenanthrene-type dication 2a2+ upon oxidation. It is shown that the redox pair of 1a and 2a2+ exhibits electrochromism accompanied by reversible C-C bond making/breaking. On the other hand, the binaphthyl derivative of 1a is chiral due to the axial chirality, thus realizing a chiroptical response by electron transfer. The title compounds were shown to be a useful skeleton to obtain the multi-output response system based on chiral redox systems, for which only a limited numbers of successful examples were reported.

AB - A biphenyl-type electron donor 1a with two diarylmethylene chromophores was prepared, which gave a dihydrophenanthrene-type dication 2a2+ upon oxidation. It is shown that the redox pair of 1a and 2a2+ exhibits electrochromism accompanied by reversible C-C bond making/breaking. On the other hand, the binaphthyl derivative of 1a is chiral due to the axial chirality, thus realizing a chiroptical response by electron transfer. The title compounds were shown to be a useful skeleton to obtain the multi-output response system based on chiral redox systems, for which only a limited numbers of successful examples were reported.

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JF - 基礎有機化学討論会要旨集（基礎有機化学連合討論会予稿集）

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