Electrodeposition behavior of Zn-Ni Alloy from alkaline zincate solution

Hiroaki Nakano, Shingo Arakawa, Yuya Takada, Satoshi Oue, Shigeo Kobayashi

研究成果: ジャーナルへの寄稿記事

6 引用 (Scopus)

抄録

Electrodeposition behavior of Zn-Ni alloys was investigated at current densities of 10 to 500 A m- 2 and at amount of charge of 5 × 10 4 Cm -2 in unagitated zincate solution containing triethanolamine to form a stable complex with Ni 2+ ions at 308 K. At low current densities, the deposition of Zn-Ni alloy showed a normal type codeposition, in which electrochemically more noble Ni deposited preferentially, while at high current densities, it showed an anomalous codeposition, in which less noble Zn deposited preferentially. The Ni deposition and H 2 evolution were significantly suppressed in the region of anomalous codeposition at high current densities, showing the formation of inhibitor of deposition resulting from Zn ions in the cathode layer. In the region of nor-mal codeposition at low current densities, the underpotential deposition of Zn apparently occurred with Ni. Because the Zn-Ni alloys are composed of stable intermetallic compound of Ni 5Zn 21, the activity coefficient of Zn in deposit seems to decrease remarkably.

元の言語英語
ページ(範囲)443-448
ページ数6
ジャーナルNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
76
発行部数7
DOI
出版物ステータス出版済み - 7 1 2012

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Electrodeposition
electrodeposition
Current density
current density
low currents
high current
Ions
Triethanolamine
Activity coefficients
inhibitors
Intermetallics
intermetallics
ions
Cathodes
Deposits
cathodes
deposits
coefficients

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

これを引用

Electrodeposition behavior of Zn-Ni Alloy from alkaline zincate solution. / Nakano, Hiroaki; Arakawa, Shingo; Takada, Yuya; Oue, Satoshi; Kobayashi, Shigeo.

:: Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 巻 76, 番号 7, 01.07.2012, p. 443-448.

研究成果: ジャーナルへの寄稿記事

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abstract = "Electrodeposition behavior of Zn-Ni alloys was investigated at current densities of 10 to 500 A m- 2 and at amount of charge of 5 × 10 4 Cm -2 in unagitated zincate solution containing triethanolamine to form a stable complex with Ni 2+ ions at 308 K. At low current densities, the deposition of Zn-Ni alloy showed a normal type codeposition, in which electrochemically more noble Ni deposited preferentially, while at high current densities, it showed an anomalous codeposition, in which less noble Zn deposited preferentially. The Ni deposition and H 2 evolution were significantly suppressed in the region of anomalous codeposition at high current densities, showing the formation of inhibitor of deposition resulting from Zn ions in the cathode layer. In the region of nor-mal codeposition at low current densities, the underpotential deposition of Zn apparently occurred with Ni. Because the Zn-Ni alloys are composed of stable intermetallic compound of Ni 5Zn 21, the activity coefficient of Zn in deposit seems to decrease remarkably.",
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AU - Nakano, Hiroaki

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AU - Kobayashi, Shigeo

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N2 - Electrodeposition behavior of Zn-Ni alloys was investigated at current densities of 10 to 500 A m- 2 and at amount of charge of 5 × 10 4 Cm -2 in unagitated zincate solution containing triethanolamine to form a stable complex with Ni 2+ ions at 308 K. At low current densities, the deposition of Zn-Ni alloy showed a normal type codeposition, in which electrochemically more noble Ni deposited preferentially, while at high current densities, it showed an anomalous codeposition, in which less noble Zn deposited preferentially. The Ni deposition and H 2 evolution were significantly suppressed in the region of anomalous codeposition at high current densities, showing the formation of inhibitor of deposition resulting from Zn ions in the cathode layer. In the region of nor-mal codeposition at low current densities, the underpotential deposition of Zn apparently occurred with Ni. Because the Zn-Ni alloys are composed of stable intermetallic compound of Ni 5Zn 21, the activity coefficient of Zn in deposit seems to decrease remarkably.

AB - Electrodeposition behavior of Zn-Ni alloys was investigated at current densities of 10 to 500 A m- 2 and at amount of charge of 5 × 10 4 Cm -2 in unagitated zincate solution containing triethanolamine to form a stable complex with Ni 2+ ions at 308 K. At low current densities, the deposition of Zn-Ni alloy showed a normal type codeposition, in which electrochemically more noble Ni deposited preferentially, while at high current densities, it showed an anomalous codeposition, in which less noble Zn deposited preferentially. The Ni deposition and H 2 evolution were significantly suppressed in the region of anomalous codeposition at high current densities, showing the formation of inhibitor of deposition resulting from Zn ions in the cathode layer. In the region of nor-mal codeposition at low current densities, the underpotential deposition of Zn apparently occurred with Ni. Because the Zn-Ni alloys are composed of stable intermetallic compound of Ni 5Zn 21, the activity coefficient of Zn in deposit seems to decrease remarkably.

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