Electrodeposition of Zn-Zr oxide composite from dispersed particles-free solution

Hiroaki Nakano, Yosuke Hara, Satoshi Oue, Shigeo Kobayashi

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

Electrodeposition of Zn-Zr oxide composite was examined from an unagitated sulfate solution containing Zn2+ and Zr ions at pH 1 to 2 and 313 K under galvanostatic conditions. Zr content in deposits was higher in pH 2 than that in pH 1, and decreased for the moment with increasing current density, but the further increase in current density brought about the increase in Zr content in deposits. This increase in Zr content in deposits is attributed to the acceleration of the hydrolysis of Zr ions by means of an increase in hydrogen evolution in the cathode layer. In solution containing Zr ions, Zn deposition was significantly polarized due to the film resistance of Zr oxide formed by the hydrolysis of Zr ions. The pH in the vicinity of the cathode, as measured by an Sb microelectrode, was approximately 2.2, which is close to the critical pH for the formation of ZrO2. SEM and EDX point analysis of deposits revealed that the granular Zr oxide deposited at the surface of Zn platelet crystals and at the void between the Zn platelet crystals. It was found from the polarization curves in 3 mass% NaCl solution that the corrosion potential of deposited Zn-1.1 mass% Zr oxide films was more noble than that of pure Zn, and the corrosion current density of Zn-1.1 mass% Zr oxide films was lower than that of pure Zn.

元の言語英語
ページ(範囲)151-156
ページ数6
ジャーナルNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
80
発行部数2
DOI
出版物ステータス出版済み - 1 1 2016

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Electrodeposition
electrodeposition
Oxides
Deposits
Ions
Current density
deposits
composite materials
oxides
Composite materials
Platelets
Oxide films
Hydrolysis
current density
platelets
Cathodes
oxide films
hydrolysis
Corrosion
corrosion

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

これを引用

Electrodeposition of Zn-Zr oxide composite from dispersed particles-free solution. / Nakano, Hiroaki; Hara, Yosuke; Oue, Satoshi; Kobayashi, Shigeo.

:: Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 巻 80, 番号 2, 01.01.2016, p. 151-156.

研究成果: ジャーナルへの寄稿記事

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abstract = "Electrodeposition of Zn-Zr oxide composite was examined from an unagitated sulfate solution containing Zn2+ and Zr ions at pH 1 to 2 and 313 K under galvanostatic conditions. Zr content in deposits was higher in pH 2 than that in pH 1, and decreased for the moment with increasing current density, but the further increase in current density brought about the increase in Zr content in deposits. This increase in Zr content in deposits is attributed to the acceleration of the hydrolysis of Zr ions by means of an increase in hydrogen evolution in the cathode layer. In solution containing Zr ions, Zn deposition was significantly polarized due to the film resistance of Zr oxide formed by the hydrolysis of Zr ions. The pH in the vicinity of the cathode, as measured by an Sb microelectrode, was approximately 2.2, which is close to the critical pH for the formation of ZrO2. SEM and EDX point analysis of deposits revealed that the granular Zr oxide deposited at the surface of Zn platelet crystals and at the void between the Zn platelet crystals. It was found from the polarization curves in 3 mass{\%} NaCl solution that the corrosion potential of deposited Zn-1.1 mass{\%} Zr oxide films was more noble than that of pure Zn, and the corrosion current density of Zn-1.1 mass{\%} Zr oxide films was lower than that of pure Zn.",
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