抄録
The electron-rich diplatinum (0) and dipaladium (0) complexes were synthesized to establish an 18-valence-electron configuration. The encapsulation of acidic hydrides into the cage was readily promoted, leading to the mono- and dihydride complexes. The detailed structural examination revealed the steric communication mechanism between the long-separated Pt centers. A similar mechanism was presumed to be evident in the two irreversible, suggesting that the electrochemical behavior can be switched by the stepwise hydride masking.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 6042-6051 |
| ページ数 | 10 |
| ジャーナル | Organometallics |
| 巻 | 23 |
| 号 | 25 |
| DOI | |
| 出版ステータス | 出版済み - 12月 6 2004 |
| 外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 物理化学および理論化学
- 有機化学
- 無機化学