Electron-rich diplatinum(0) metallocryptate promoting novel successive encapsulation of acidic hydrides

Eri Goto, Miho Usuki, Hiroe Takenaka, Ken Sakai, Tomoaki Tanase

研究成果: ジャーナルへの寄稿学術誌査読

14 被引用数 (Scopus)

抄録

The electron-rich diplatinum (0) and dipaladium (0) complexes were synthesized to establish an 18-valence-electron configuration. The encapsulation of acidic hydrides into the cage was readily promoted, leading to the mono- and dihydride complexes. The detailed structural examination revealed the steric communication mechanism between the long-separated Pt centers. A similar mechanism was presumed to be evident in the two irreversible, suggesting that the electrochemical behavior can be switched by the stepwise hydride masking.

本文言語英語
ページ(範囲)6042-6051
ページ数10
ジャーナルOrganometallics
23
25
DOI
出版ステータス出版済み - 12月 6 2004
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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