Electronic structures and electrochemical properties of LiPF6-n(CF3)n

Fusaji Kita, Hideo Sakata, Akira Kawakami, Haruki Kamizori, Takaaki Sonoda, Hideo Nagashima, Natalya V. Pavlenko, Yurii L. Yagupolskii

研究成果: ジャーナルへの寄稿Conference article

32 引用 (Scopus)

抜粋

We evaluated (1) thermal and electrochemical stability and (2) ion-dissociation ability of PF6-n(CF3)n- anions by computational method. The thermal stability order by ΔΔE (anion) is PF4(CF3)2- > PF5(CF3)- > PF3(CF3)3- > PF6-. The ion-dissociation ability order by ΔΔE (Li salts) is LiPF3(CF3)3 > LiPF4(CF3)2 > LiPF5(CF3) > LiPF6. The conductivity of electrolyte solution with LiPF4(CF3)2 (3.9 mS/cm) was a little lower than that of LiPF6 (4.4 mS/cm) in 0.1 mol/l Li salt/PC:DME electrolyte, while the oxidation potential of LiPF4(CF3)2 in PC was higher than that of LiPF6. The LiPF4(CF3)2-cell showed better cycle characteristics than LiPF6-cell.

元の言語英語
ページ(範囲)581-583
ページ数3
ジャーナルJournal of Power Sources
97-98
DOI
出版物ステータス出版済み - 7 1 2001
イベント10th International Meeting on Lithium Batteries - Como, イタリア
継続期間: 5 28 20016 2 2001

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

これを引用

Kita, F., Sakata, H., Kawakami, A., Kamizori, H., Sonoda, T., Nagashima, H., ... Yagupolskii, Y. L. (2001). Electronic structures and electrochemical properties of LiPF6-n(CF3)n. Journal of Power Sources, 97-98, 581-583. https://doi.org/10.1016/S0378-7753(01)00695-4