Electrophoresis of electrically neutral porous spheres induced by selective affinity of ions

研究成果: Contribution to journalArticle査読

11 被引用数 (Scopus)

抄録

I investigate the possibility that electrically neutral porous spheres electrophorese in electrolyte solutions with asymmetric affinity of ions to spheres on the basis of electrohydrodynamics and the Poisson-Boltzmann and Debye-Bueche-Brinkman theories. Assuming a weak electric field and ignoring the double-layer polarization, I obtain analytical expressions for electrostatic potential, electrophoretic mobility, and flow field. In the equilibrium state, the Galvani potential forms across the interface of the spheres. Under a weak electric field, the spheres show finite mobility with the same sign as the Galvani potential. When the radius of the spheres is significantly larger than the Debye and hydrodynamic screening length, the mobility monotonically increases with increasing salinity.

本文言語英語
論文番号022303
ジャーナルPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
91
2
DOI
出版ステータス出版済み - 2 9 2015
外部発表はい

All Science Journal Classification (ASJC) codes

  • 統計物理学および非線形物理学
  • 統計学および確率
  • 凝縮系物理学

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